Download e-book for kindle: Advances in Inorganic Chemistry, Vol. 29 by H.J. Emeléus, A.G. Sharpe (Eds.)

By H.J. Emeléus, A.G. Sharpe (Eds.)

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I11. Hydrldes . . . . . . . . . . Structures . . . . . . . . . . A . Mononuclear Complexes . . . . . . . B. Dinuclear Complexes . . . . . . . . V . Bonding . . . . . . . . . . A . Trifluorophosphine . . . . . . . . B. Transition Metal-PF, Complexes . . . . . . C. PF, Adsorbed on Metal Surfaces . . . . . . D . Comparison of CO and PF, as Ligands . . . . . VI . Dinuclear Complexes Containing Bridging PF, Ligands . . . VII .

Proc. Natl. ,Repub. China, Pt. B 5,344 (1981). 54. Huheey, J. , “Inorganic Chemistry,” p. Harper, New York, 1974. 55. Hwang, T. , and Liu, C. , J . Am. Chem. Soe. 102,385 (1980). 56a. , Pai, Y. , and Liu, C . , J. Am. Chem. 102,7519 (1980). 56b. Hwangs T. D. Thesis, National Tsing Hua University, Hsinchu, Taiwan (1980). 57. , Setchaku 21,162 (1977). 58. , J. Organomet. Chem. 142, C45 (1977). 59. , p. Academic Press, New York, 1971. 60. , Kem. Kozl. 52,347 (1979). 61. , M. S. Thesis, National Tsing Hua University, Hsinchu, Taiwan (1983).

The most interesting result is the fact that both reactions appear to be nonstereospecific. The relative abundances of the various isomers of the insertion products are shown in Table 11. TABLE I1 RELATIVE YIELDS OF THE VOLATILE PRODUCTS OF THE REACTIONS WITH trans- AND cis-CHF=CHF IN VARIOUS CONDITIONS Relative yield” (yo) Cocondensation Alternate layer cisb cisb Reaction product trans-CHF=CHSiF, 5 trans‘ 6 (77) cis-CHF=CHSiF, trans-CHF=CHSiF,SiF, 6 18 10 43 (77) (88) cis-CHF=CHSiF,SiF, 44 trans-CHF=CHSiF,SiF,SiF, 2 13 13 (81) (93) cis-CHF=CHSiF,SiF,SiF, 26 cisb trans‘ 64 64 36 36 (64) (78) 21 17 trans‘ Gas phase 3 Numbers in parentheses are the percentage of configuration retention.

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